Msds_impralan-grund_g100

Safety data sheet
according to 1907/2006/EC, Article 31
1 Identification of the substance/mixture and of the company/undertaking
• Product identifier
• Trade name: impralan-Grund G100 0000 farblos
• Article number: W702401
• Relevant identified uses of the substance or mixture and uses advised against
• Application of the substance / the preparation
• Details of the supplier of the safety data sheet
• Manufacturer/Supplier:
RÜTGERS Organics GmbHOppauer Straße 43D-68305 MannheimTel.: **49-621-76540US: 1-980-253-8880Fax : **49-621-7654446e-mail: SDB.rog@ruetgers-organics.de • Informing department: see: Heading 16 (Contact)
• Emergency telephone number: see: Manufacturer/Supplier
2 Hazards identification
• Classification of the substance or mixture
• Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects. • Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic • Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classificationguideline for preparations of the EU" in the latest valid version. • Classification system:
The classification is in line with current EC lists. It is expanded, however, by information fromtechnical literature and by information furnished by supplier companies. • Label elements
• Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation. • Hazard pictograms GHS09
• Signal word Warning
• Hazard statements
H410 Very toxic to aquatic life with long lasting effects.
Contains 3-Iodo-2-propynylbutylcarbamate, Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo(4,5-d)imidazole-2,5(1H,3H)-dione, permethrin (ISO). May produce an allergic reaction. • Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P273 Avoid release to the environment.
P391 Collect spillage. Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
P501 Dispose of contents/container in accordance with local/regional/national/international • Other hazards
• Results of PBT and vPvB assessment
• PBT: Not applicable.
• vPvB: Not applicable.
3 Composition/information on ingredients
• Chemical characterization: Mixtures
• Description: Mixture consisting of the following components.
• Dangerous components:
Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo(4,5-d) < 0.5% Aquatic Acute 1, H400; Aquatic Chronic 1, H410; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin Sens. 1, • Additional information For the wording of the listed risk phrases refer to section 16.
4 First aid measures
• Description of first aid measures
• After inhalation Supply fresh air; consult doctor in case of symptoms.
• After skin contact If skin irritation continues, consult a doctor.
• After eye contact Rinse opened eye for several minutes under running water.
• After swallowing In case of persistent symptoms consult doctor.
• Information for doctor No particular measures are known - treat according to symptoms.
• Most important symptoms and effects, both acute and delayed
No further relevant information available. • Indication of any immediate medical attention and special treatment needed
No further relevant information available. 5 Firefighting measures
• Extinguishing media
• Suitable extinguishing agents Use fire fighting measures that suit the environment.
• Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire. • Advice for firefighters
• Protective equipment: Wear self-contained breathing apparatus.
• Additional information Collect contaminated fire fighting water separately. It must not enter drains.
6 Accidental release measures
• Personal precautions, protective equipment and emergency procedures Not required.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• Environmental precautions:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
Dilute with much water. • Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). • Reference to other sections
See Section 7 for information on safe handlingSee Section 8 for information on personal protection equipment.
See Section 13 for information on disposal. 7 Handling and storage
• Handling
• Precautions for safe handling Precautions against electrostatic charging.
• Information about protection against explosions and fires: No special measures required.
• Conditions for safe storage, including any incompatibilities
• Storage
• Requirements to be met by storerooms and containers:
Store only in the original container.
Prevent any penetration into the ground. • Information about storage in one common storage facility: Store away from foodstuffs.
• Further information about storage conditions: Protect from frost.
• Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
• Additional information about design of technical systems: No further data; see item 7.
• Control parameters
• Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to bemonitored at the workplace.
Not required. 111-76-2 2-butoxyethanol (< 0.5%)
WEL Short-term value: 50 ppm
7664-41-7 ammonia, anhydrous (< 0.01%)
WEL Short-term value: 25 mg/m³, 35 ppm
Long-term value: 18 mg/m³, 25 ppm • Additional information: The lists that were valid during the compilation were used as basis.
• Exposure controls
• Personal protective equipment
• General protective and hygienic measures
Wash hands during breaks and at the end of the work. • Breathing equipment: Not required.
• Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ thepreparation.
Due to missing tests no recommendation to the glove material can be given for the product/ thepreparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and thedegradation Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marksof quality and varies from manufacturer to manufacturer. As the product is a preparation of severalsubstances, the resistance of the glove material can not be calculated in advance and has thereforeto be checked prior to the application. • Penetration time of glove material
The exact breaktrough time has to be found out by the manufacturer of the protective gloves andhas to be observed. • Eye protection: Safety glasses recommended during refilling.
• Body protection: Protective work clothing.
9 Physical and chemical properties
• Information on basic physical and chemical properties
• General Information
• Appearance:
Form:
Colour:
• Odour:
• Odour threshold:
• pH-value at 20°C:
• Change in condition
Melting point/Melting range:
Boiling point/Boiling range:
• Flash point:
• Inflammability (solid, gaseous)
• Ignition temperature:
Decomposition temperature:
• Self-inflammability:
• Danger of explosion:
• Critical values for explosion:
Lower:
Upper:
• Vapour pressure at 20°C:
• Density at 20°C
• Relative density
• Vapour density
• Evaporation rate
• Solubility in / Miscibility with
Water:
• Segregation coefficient (n-octanol/water): Not determined.
• Viscosity:
dynamic:
kinematic at 20°C:
• Solvent content:
Organic solvents:
Water:
Solids content:
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• Other information
No further relevant information available. 10 Stability and reactivity
• Reactivity
• Chemical stability
• Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications. • Possibility of hazardous reactions No dangerous reactions known
• Conditions to avoid No further relevant information available.
• Incompatible materials: No further relevant information available.
• Hazardous decomposition products: No dangerous decomposition products known
11 Toxicological information
• Information on toxicological effects
• Acute toxicity:
• LD/LC50 values that are relevant for classification:
52645-53-1 permethrin (ISO)
Oral
1479 mg/kg (Rattus norvegicus (Ratte)) >4000 mg/kg (Oryctolagus cuniculus (eur. Kaninchen)) >2000 mg/kg (Rattus norvegicus (Ratte)) Inhalative LC50/4 h > 0.599 mg/l (Rattus norvegicus (Ratte)) • Primary irritant effect:
• on the skin: No irritant effect.
• on the eye: No irritant effect.
• Sensitization: No sensitizing effect known.
12 Ecological information
• Toxicity
• Aquatic toxicity:
52645-53-1 permethrin (ISO)
IC50
0.5 mg/l (Selenastrum capricornutum) LC50(96 h) 0.0076 mg/l (Poecilia reticulata) • Persistence and degradability No further relevant information available.
• Behaviour in environmental systems:
• Bioaccumulative potential No further relevant information available.
• Mobility in soil No further relevant information available.
• Remark: Very toxic for fish
• Additional ecological information:
• General notes:
At present there are no ecotoxicological assessments.
This statement was deduced from the properties of the single components.
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water.
Do not allow product to reach ground water, water bodies or sewage system.
Danger to drinking water if even small quantities leak into soil.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms • Results of PBT and vPvB assessment
• PBT: Not applicable.
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• vPvB: Not applicable.
• Other adverse effects No further relevant information available.
13 Disposal considerations
• Waste treatment methods
• Recommendation
Remove in accordance with the local official recommendations.
Must not be disposed of together with household garbage. Do not allow product to reach sewagesystem. • European waste catalogue
03 00 00 WASTES FROM WOOD PROCESSING AND THE PRODUCTION OF PANELS AND FURNITURE, PULP, PAPER AND CARDBOARD 03 02 00 wastes from wood preservation 03 02 02* organochlorinated wood preservatives • Uncleaned packagings:
• Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
• Substance Index Number
• ADR, IMDG, IATA
• ADN
• UN proper shipping name
• ADR
3 0 8 2 E N V I R O N M E N T A L L Y H A Z A R D O U SS U B S T A N C E , L I Q U I D , N . O . S . ( 3 - I o d o - 2 -propynylbutylcarbamate, permethrin (ISO)) • ADN
• IMDG
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (3-Iodo-2-propynylbutylcarbamate,permethrin (ISO)), MARINE POLLUTANT • IATA
ENVIRONMENTALLY HAZARDOUS SUBSTANCE,LIQUID, N.O.S. (3-Iodo-2-propynylbutylcarbamate,permethrin (ISO)) • Transport hazard class(es)
• ADR, IMDG, IATA
• Class
9 Miscellaneous dangerous substances and articles. • Label
• ADN/R Class:
• Packing group
• ADR, IMDG, IATA
• Environmental hazards:
Pr odu ct c ont ain s en viron men tally h aza rdo ussubstances: 3-Iodo-2-propynylbutylcarbamate,permethrin (ISO) • Marine pollutant:
• Special marking (ADR):
Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• Special marking (IATA):
• Special precautions for user
Warning: Miscellaneous dangerous substances andarticles. • Hazard Index Number:
• EMS Number:
• Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code
• Transport/Additional information:
Not a dangerous good in accordance with nationaland international regulations. • ADR
• Tunnel restriction code
• UN "Model Regulation":
UN 30 82 , ENVI RO NMENT AL LY HAZAR DO USS U B S T A N C E , L I Q U I D , N . O . S . ( 3 - I o d o - 2 -propynylbutylcarbamate, permethrin (ISO)), 9, III 15 Regulatory information
• Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee forany specific product features and shall not establish a legally valid contractual relationship.
It is the responsibility of the user to assure himself that the information provided with this materialsafty data sheet is complete and applicable for his utilization of the product. • Relevant phrases
May cause an allergic skin reaction. Very toxic to aquatic life with long lasting effects. R20/22 Harmful by inhalation and if swallowed.
R37 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic • Department issuing data specification sheet: Product safety department, Mannheim
• Contact:
RÜTGERS OrganicsProduct SafetyTel. **49 / 621 7654 247 • Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning theInternational Carriage of Dangerous Goods by Road)RID: Règlement international concernant le transport des marchandises dangereuses par chemin de fer (RegulationsConcerning the International Transport of Dangerous Goods by Rail)IMDG: International Maritime Code for Dangerous GoodsIATA: International Air Transport AssociationICAO: International Civil Aviation OrganizationGHS: Globally Harmonized System of Classification and Labelling of ChemicalsLC50: Lethal concentration, 50 percent Safety data sheet
according to 1907/2006/EC, Article 31
Trade name: impralan-Grund G100 0000 farblos
• * Data compared to the previous version altered.

Source: http://www.agwoodcare.co.uk/pdf/impra/msds/MSDS_impralan-Grund_G100.pdf