Document

SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
1. Identification of the substance/mixture and of the company/undertaking
Product identifier
Identification / trade name:
REACH registration number:
Relevant identified uses of the substance or mixture and uses advised against
Use of the substance / mixture:
Details of the supplier of the safety data sheet
Supplier / Manufacturer:
Telephone:
Telefax:
Department responsible for information
Information contact:
E-mail (competent person):
Emergency telephone:
0049-8141-51030 (only during office hours) 2. Hazards identification
Classification of the substance or mixture
Classification according to 67/548/EEC or 1999/45/EC
Harmful (Xn), Dangerous for the environment (N), R43-50/53-65-66 Label elements
Labelling according to 67/548/EEC or 1999/45/EC
This preparation is classified as hazardous according to 1999/45/EG.
Hazard symbols and hazard statements
Xn - Harmful, N - Dangerous for the environment R-phrases
R43 May cause sensitisation by skin contact.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
S-phrases
S2 Keep out of the reach of children.
S13 Keep away from food, drink and animal feedingstuffs.
S36/37 Wear suitable protective clothing and gloves.
S60 This material and its container must be disposed of as hazardous waste.
S61 Avoid release to the environment. Refer to special instructions/safety data sheets.
S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.
Hazard components for labeling
Permethrin, Tetramethrin, Piperonyl butoxide, Hydrocarbons 3. Composition / information on ingredients
Chemical characterization
Mixture of pyrethroids, synergistic compounds and aliphatic hydrocarbons.
Hazardous ingredients
90 - 100 % Hydrocarbons aliphatic, CAS 68551-17-7, Symbol Xn, R-phrases 65-661.0 - 5.0 % 2-(2-Butoxyethoxy)-ethanol, CAS 112-34-5, Symbol Xi, R-phrase 361.0 - 2.0 % Permethrin 25:75 cis:trans, CAS 52645-53-1, Symbol Xn, N, R-phrases 20/22-43-50/530.1 - 1.0 % Tetramethrin, CAS 7696-12-0, Symbol Xn, N, R-phrases 20-50/530.1 - 1.0 % Piperonyl butoxide, CAS 51-03-6, Symbol N, R-phrases 51/53 Full text of R- and H-phrases: see section 16.
4. First aid measures
General informations:
In all cases of doubt, or when symptoms persist, seek medical advice.
In case of inhalation:
Remove from exposure site to fresh air and obtain medical advice.
In case of skin contact:
Wash thoroughly with water and soap.
In case of eye contact:
Flush immediately with plenty of water. Contact physician if symptoms persist.
In case of ingestion:
Do not induce vomitting, obtain medical advice.
5. Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water mist / foam / carbondioxide / dry chemical Unsuitable extinguishing media:
Special hazards arising from the substance or mixture
Carbonoxides may be formed during combustion.
SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
Advice for fire-fighters
6. Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid inhalation and contact with skin and eyes.
Environmental precautions
Large quantities of product should not get into drains, surface- and groundwater.
Methods and material for containment and cleaning up
Absorb with an absorbent material and dispose of according to local regulations.
Reference to other sections
Observe protective measures in sections 7 and 8.
7. Handling and Storage
Precautions for safe handling
Advices on safe handling
Avoid contact with skin and eyes. Good general ventilation should be provided.
Precautions against fire and explosion
Keep away from ignition sources and naked flame, do not smoke.
Flammable vapour/air-mixtures may be formed.
Conditions for safe storage, including any incompatibilities
Information on storage conditions
Store in tightly closed original container in a dry and cool place.
Requirements for storage rooms and vessels
Keep container tightly closed in a cool, well-ventilated place.
8. Exposure controls / Personal protection
Control parameters
Hydrocarbon mixture, C9-C15 Aliphatics, occupational exposure limit 600 mg/m³ SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
Exposure controls
Technical measures
See section 7. No additional measures necessary.
Personal protection equipment
Respiratory protection:
In case of excessive vapours wear a respirator mask filter A2.
Hand protection:
Tested gloves with breakthrough time >= 8 hours made from NBR (0.35 mm) or FKM(0.4 mm) Eye protection:
Protective clothing:
General health and safety measures
Respect good personal hygiene. Do not drink, eat or smoke while handling.
Environmental exposure controls
9. Physical and chemical properties
Information on basic physical and chemical properties
General information
Physical state:
Freezing point (°C):
Boiling temperature (°C):
Flashpoint (°C):
Vapour pressure (hPa):
Density (g/cm³):
Water solubility:
Fat solubility:
Dynamic viscosity (mPas):
Other information
No other physical and chemical data has been recorded.
SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
10. Stability and Reactivity
Reactivity
No decomposition if used and stored according to specifications.
Chemical stability
Possibility of hazardous reactions
There are expected no hazardous reactions for intended use.
Conditions to avoid
Incompatible materials
Hazardous decomposition products
Carbonoxides may be formed during combustion.
11. Toxicological information
Information on toxicological effects
Irritant and corrosive effects
Slightly irritant but not relevant for classification.
Sensitisation
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
No CMR activities known or suspected.
Additional information
Prolonged exposure may cause skin irritation.
12. Ecological information
Toxicity
Persistence and degradability
Product is potentially biodegradable.
Bioaccumulative potential
SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
Mobility in soil
Other adverse effects
13. Disposal considerations
Waste treatment methods
Recommendation
Dispose of according to local regulations.
Waste codes/waste designations according to EWC
Packaging
Contaminated package
Dispose of according to local regulations.
Cleaned package
Non contaminated and clean packagings can be used for recycling.
14. Transport information
Land transport (ADR/RID)
No dangerous good in sense of this transport regulation.
Sea transport (IMDG)
No dangerous good in sense of this transport regulation.
Air transport (ICAO-TI / IATA-DGR)
No dangerous good in sense of this transport regulation.
15. Regulatory information
Safety, health and environmental regulations/legislation specific for the substance or mixture
National regulations
SAFETY DATA SHEETaccording to Regulation (EC) No 1907/2006 (REACH) Art. 2280, INSEKT-EX
Chemical Safety Assessment
For this mixture a chemical safety assessment has not been carried out.
16. Other information
Relevant R-phrases (number and full text)
R20 Harmful by inhalation.
R22 Harmful if swallowed.
R36 Irritating to eyes.
R43 May cause sensitisation by skin contact.
R50 Very toxic to aquatic organisms.
R51 Toxic to aquatic organisms.
R53 May cause long-term adverse effects in the aquatic environment.
R65 Harmful: may cause lung damage if swallowed.
R66 Repeated exposure may cause skin dryness or cracking.
Data sources
The above information describes exclusively the safety requirements of the product and is based on ourpresent-day knowledge. The information is intended to give you advice about the safe handling of the productnamed in this safety data sheet, for storage, processing, transport and disposal.

Source: http://www.hwr-chemie.de/download/en_sdb/2280_sdb_engl.pdf