MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784 1. PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: EVERCIDE® Permethrin 10% EC 2784 PRODUCT DESCRIPTION: A Long Lasting Livestock and Premise Spray. PRODUCT CODE: 002784, EPA REG. NO. : 1021-1736 ACTIVE INGREDIENT(S): Permethrin MANUFACTURER 24 HR. EMERGENCY TELEPHONE NUMBERS CHEMTREC U.S. and CANADA:(800) 424-9300 CHEMTREC All Other Areas:(703) 527-3887 Emergency Phone:(888) 740-8712 Service Number: (800) 645-6466 Alternate Emergency Phone:(952) 852-9509 Alternate Customer Service: (763) 544-0341 COMMENTS: MGK® Hours of operation are 8:00 am to 4:30 pm CST, 14:00 to 22:30 GMT.
For MEDICAL EMERGENCIES or PESTICIDE INCIDENTS, call 24 hours a day to 1-888-740-8712. 2. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW IMMEDIATE CONCERNS: CAUTION. Harmful if swallowed or absorbed through the skin. Causes moderate eye
irritation. Avoid contact with skin, eyes, and clothing.
DO NOT use this product in or on electrical equipment due to the possibility of shock hazard. POTENTIAL HEALTH EFFECTS EYES: Causes moderate eye irritation. SKIN: Can cause skin irritation. Can cause a burning or prickling sensation on more sensitive areas (face, eyes, SKIN ABSORPTION: Harmful if absorbed through the skin. INGESTION: Harmful if swallowed. INHALATION: Excessive inhalation may be irritating to the respiratory tract. SIGNS AND SYMPTOMS OF OVEREXPOSURE CHRONIC EFFECTS: None known. COMMENTS: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 3. COMPOSITION / INFORMATION ON INGREDIENTS Chemical Name COMMENTS: Ingredients not identified are proprietary or non-hazardous. Values are not product specifications. 4. FIRST AID MEASURES MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784 EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after
the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. SKIN: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison
control center or doctor for treatment advice. INGESTION: If swallowed, IMMEDIATELY call a poison control center or doctor for treatment advice. DO NOT give any
liquid to the person. Do not induce vomiting unless told to do so by a poison contol center or a doctor. Never giveanything by mouth to an unconscious person. INHALATION: Remove affected person to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatmentadvice. NOTES TO PHYSICIAN: For skin effects, a highly efficient therapeutic agent for pyrethroid exposure is topical
application of tocopherol acetate (Vitamin E). 5. FIRE FIGHTING MEASURES FLASHPOINT AND METHOD: > 93.3°C (200°F) TAG Closed Cup FLAMMABLE CLASS: This product is NOT classified as flammable or combustible by OSHA. EXTINGUISHING MEDIA: Use water spray, foam, carbon dioxide or dry chemical. HAZARDOUS COMBUSTION PRODUCTS: This product is classified as Non-Combustible, however in the extreme
temperatures that fires may produce, some of the constituents of this formula may combust to give off toxic gases suchas carbon dioxide, carbon monoxide, nitrogen oxides, Hydrogen Chloride, and Chlorine gas. FIRE FIGHTING PROCEDURES: Treat as an oil fire. Use a full-faced self-contained breathing apparatus along with full
protective gear. Keep nearby containers and equipment cool with a water stream. 6. ACCIDENTAL RELEASE MEASURES SMALL SPILL: Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can
prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Absorb with appropriate absorbent such as sand, or vermiculite. Clean spill area of residues and absorbent. LARGE SPILL: Stop release, if possible without risk. Dike or contain release, if possible, and if immediate response can
prevent further damage or danger. Isolate and control access to the release area. Take actions to reduce vapors. Collect product into drums, storage tanks, etc., via drains, pumps, etc. Absorb with appropriate absorbent such assand or vermiculite. Clean spill area of residues and absorbent. ENVIRONMENTAL PRECAUTIONS WATER SPILL: Contains pyrethroids which are toxic to fish and other aquatic invertebrates. Contaminated absorbent
and wash water should be disposed of according to local, state/provincial and federal/national regulations. 7. HANDLING AND STORAGE GENERAL PROCEDURES: DO NOT USE IN OR AROUND ELECTRICAL EQUIPMENT DUE TO THE POSSIBILITY
OF SHOCK HAZARD. Do not use or store near heat, sparks, open flame, or any other ignition sources. HANDLING: Take prudent precautions to avoid contact with skin, eyes, and clothing. Do not contaminate water, food or
feedstuffs, by storage, handling, or by disposal. Read and observe all precautions and instructions on the label. STORAGE: Store container closed, upright, and at room temperature. Avoid exposure to extreme temperatures. Always
store pesticides in the original container. Store away from food, pet food, feed, seed, fertilizers, and veterinarysupplies. Place liquid formulations on lower shelves, and dry formulations above. MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784 KEEP OUT OF REACH OF CHILDREN 8. EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES OSHA HAZARDOUS COMPONENTS (29 CFR1910.1200) EXPOSURE LIMITS ACGIH TLV SupplierOEL Chemical Name OSHA TABLE COMMENTS: 1. As oil-mist, if generated. ENGINEERING CONTROLS: Ventilate treatment area thoroughly before re-entry. PERSONAL PROTECTIVE EQUIPMENT EYES AND FACE: Take prudent precautions to avoid contact with eyes. SKIN: Take prudent precautions to avoid contact with skin and clothing. WORK HYGIENIC PRACTICES: DO NOT SMOKE, EAT, OR DRINK, OR APPLY COSMETICS IN WORK AREA!
Wash promptly if skin becomes contaminated. Wash at the end of each work shift and before eating, smoking, or usingthe toilet. 9. PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE: Liquid ODOR: Slight solvent smell. APPEARANCE: Clear, amber-brown colored liquid. COLOR: 1.0 on Gardner Scale. Notes: @ 5% in water. VAPOR DENSITY: Heavier than air. FREEZING POINT: Not Determined FLASHPOINT AND METHOD: > 93.3°C (200°F) TAG Closed Cup SOLUBILITY IN WATER: Partially miscible in water. SPECIFIC GRAVITY: 0.934 (Water = 1) at 20°C (68°F) VISCOSITY #1: 11.3 CPS at 22.5°C (72.5°F) Brookfield (VOC): < 2.000 % 10. STABILITY AND REACTIVITY STABLE: Yes MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784 HAZARDOUS POLYMERIZATION: No CONDITIONS TO AVOID: Not compatible with strong acids or bases. Not compatible with strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS: May decompose under fire or extreme temperatures to give off toxic
Chlorine gas, Hydrogen Chloride, as well as Carbon Monoxide, Carbon Dioxide, and Nitrogen Oxides.
11. TOXICOLOGICAL INFORMATION DERMAL LD50: > 2000 mg/kg Notes: Albino rabbit. ORAL LD50: > 2000 mg/kg Notes: Albino rat. INHALATION LC50: The Acute Inhalation LC50 of this material places it in EPA Toxic Category IV. EYE EFFECTS: Irritation clearing within 48 hours. SKIN EFFECTS: No irritation observed. Irritation Index = 0.0 SENSITIZATION: Negative; Not considered to be a dermal sensitizer to albino guinea pigs. GENERAL COMMENTS: Some or all of the toxicity data reported above was bridged from a substantially similar COMMENTS: None of the components present in this material at concentrations equal to or greater than 0.1% are listed
by IARC, NTP, OSHA or ACGIH as being carcinogens. 12. ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: This pesticide is extremely toxic to fish. To protect the environment, do not
allow pesticide to enter or run-off into storm drains, drainage ditches, gutters, or surface waters. Applying this productin calm weather when rain is not predicted for the next 24 hours will help to ensure that wind or rain does not blow orwash pesticide off the treatment area. Rinsing application equipment over the treated area will help avoid run-off towater bodies or drainage systems. Drift and run-off may be hazardous to aquatic organisms in water adjacent totreated areas. This product is highly toxic to bees exposed to direct treatment on blooming crops or weeds. Do notapply this product or allow it to drift to blooming crops or weeds while bees are actively visiting the treatment area. 13. DISPOSAL CONSIDERATIONS DISPOSAL METHOD: To avoid wastes, use all materials in the containers by application according to label directions. If
wastes cannot be avoided, offer remaining product to a waste disposal facility or pesticide disposal program (NOTE:such programs are often run by state or local governments, or by industry). EMPTY CONTAINER: Non-refillable container. DO NOT reuse or refill this container.
Triple-rinse container (or equivalent) promptly after emptying. Then, offer for recycling if available, or puncture anddispose of container in a sanitary landfill, or by incineration. DO NOT burn unless allowed by state and localordinances.
Triple-rinse as follows for containers less than < 5 gallons (< 18.9 L) or less: Empty the remaining contents intoapplication equipment or a mix-tank and drain for 10 seconds after the flow begins to drip. Fill the container 1/4 full withwater and re-cap. Shake for 10 seconds. Pour rinsate into application equipment or a mix-tank or store rinsate for lateruse or disposal. Drain for 10 seconds after the flow begins to drip. Repeat this procedure two more times.
Triple-rinse as follows for containers greater than > 5 gallons (> 18.9 L): Empty the remaining contents into application
MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784
equipment or a mix-tank. Fill the container 1/4 full with water. Replace and tighten closures. Tip container on its sideand roll back and forth, ensuring at least one complete revolution, for 30 seconds. Stand the container on its end andtip it back and forth several times. Turn the container over onto its other end and tip it back and forth several times. Empty the rinsate into application equipment or a mix-tank or store rinsate for later use or disposal. Repeat thisprocedure two more times. RCRA/EPA WASTE INFORMATION: None of the ingredients in this product appear on the RCRA lists (40 CFR 261.24,
40CFR 251.33) or CERCLA Hazardous Substance list (40 CFR Part 302 Table 302.4)
14. TRANSPORT INFORMATION DOT (DEPARTMENT OF TRANSPORTATION) PROPER SHIPPING NAME: Insecticides, Insect or Animal Repellent, Liquid, N.O.S. PRIMARY HAZARD CLASS/DIVISION: Non-Hazardous OTHER SHIPPING INFORMATION: This material is not regulated by the DOT as a hazardous material when shipped
in Non-Bulk quantities (i.e., less than 119 Gallon's / 450 Liter's).
When shipping in Bulk-quantities (i.e., more than 119 Gallon's / 450 Liter's), please contact MGK® for the propershipping description. AIR (ICAO/IATA) SHIPPING NAME: Insecticides, Insect or Animal Repellent, Liquid, N.O.S. PRIMARY HAZARD CLASS/DIVISION: Non-Hazardous VESSEL (IMO/IMDG) SHIPPING NAME: Not Available 15. REGULATORY INFORMATION UNITED STATES SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT) FIRE: No PRESSURE GENERATING: No REACTIVITY: No ACUTE: Yes 313 REPORTABLE INGREDIENTS: 302/304 EMERGENCY PLANNING EMERGENCY PLAN: There are no SARA Title III Section 302 extremely hazardous substances present in this
There are no components that are subject to emergency requirements under CERCLA Section 103(a)(40 CFR302.4) in this formulation. TSCA (TOXIC SUBSTANCE CONTROL ACT) TSCA STATUS: All chemical substances found in this product comply with the Toxic Substances Control Act's REGULATIONS STATE REGULATIONS: VOLATILE ORGANIC COMPOUNDS (VOC): MATERIAL SAFETY DATA SHEET Date Issued: 01/13/2000 MSDS No: 002784 Date-Revised: 05/11/2011 Revision No: 5 EVERCIDE® Permethrin 10% EC 2784
This product contains less than 2% VOC’s. 16. OTHER INFORMATION REVISION SUMMARY: Revision #: 5. This MSDS replaces the May 11, 2011 MSDS., , , , , , , , , , , Any changes in
information are as follows: In Section 2: Emergency Overview - Immediate Concerns, Potential Health Effects -IngestionIn Section 4: Notes to PhysicianIn Section 5: Flammable Class, Flash Point (Operator), Flash Point °F (From),Flash Point °C (From), Combustion Products, Sensitive Static Discharge, Fire Fighting ProceduresIn Section 6: SmallSpill, Large SpillIn Section 7: Handling, Storage, Electrostatic Accumulation HazardIn Section 8: EngineeringControlsIn Section 9: Odor, (Group Field) for Freezing Point, (Group Field) for Density, Specific Gravity (From), VOC(From)In Section 11: ToxicologicalIn Section 12: Environmental DataIn Section 13: Empty Container, DisposalInSection 15: Fire, Regulations: StateIn Section 16: HMIS Flammability
HMIS RATING FLAMMABILITY: PHYSICAL HAZARD: PERSONAL PROTECTION: HMIS RATINGS NOTES: We assign HMIS ratings to this product based on the hazards of its ingredients(s). Since the
customer is most aware of the applications and conditions of use, he or she must ensure that the proper PersonalProtective Equipment is provided, consistent with the information contained in Section's 7 and 8 of this MSDS. COMMENTS: The data contained herein are based on information currently available to McLaughlin Gormley King
Company and, to the best of our knowledge, are accurate and based on sound expert opinion. Our statements herein,however, are not to be taken as a warranty or representation for which McLaughlin Gormley King Company assumeslegal responsibility.
Stephanie J. Muga Dept. of Biology & Geology, Chemistry & Physics EDUCATION HISTORY Dates EMPLOYMENT HISTORY Dates USCA, Dept. of Biology. & Geology, Chemistry -Instructor MUSC, Dept. of Pharmacology, Charleston, SC USC School of Medicine, Dept. of Path, Micro. USC School of Medicine, Dept. of Dev. Biol. Univ. of Texas-Austin, Dept. of Human Ecology HONORS AN
vaterland 25/06/2013 Verkleinert auf 53% (Anpassung auf Papiergröße) LIECHTENSTEINER VATERLAND | DIENSTAG, 25. JUNI 2013 8 Sitzungen des E RWA C H S E N E N B I L D U N G Gastwirteprüfung bestanden Staatsgerichtshofes Mit 50 gehts erst richtig los − Wege aus dem Karriere-Blues Vaduz . –Anfang Juni wurde die liech- Vaduz. – Am 1. und 2. Juli wird d