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Mk 1003 msds

MATERIAL SAFETY DATA SHEET
Ketoconazole
NPFA
HMIS
Personal Protective Equipment
FLAMMABILITY
REACTIVITY
In Case of Emergency: Call ChemTrac (24 hr): 800-424-9300, 703-527-3887 Call (330)425-2522
1. Product Identification
Ketoconazole
Catalog Codes: MK 1003
CAS#: 65277-42-1
RTECS: TK7912300
TSCA: TSCA inventory: No products were found.
CI#: Not available.
Synonym: Piperazine,
1-acetyl-4-(4-((2-(2,4-dichlorophenyl)-2-(1H-imidazol-1-ylmethyl)-1,3-dioxolan-4-yl)methoxy)phenyl)-,cis-
Chemical Name: Ketoconazole
Chemical Formula: C26-H28-CL2-N4-O4
CHEMTREC (24HR Emergency Telephone), call:
1-800-424-9300
International CHEMTREC, call: 1-703-527-3887
For non-emergency assistance, call: 1-281-441-4400
2. Composition/Information on Ingredients
Name CAS # % by WeightKetoconazole 100Toxicological Data on Ingredients: Ketoconazole: ORAL (LD50): Acute: 166 mg/kg [Rat]. 618 mg/kg [Mouse]. 178 mg/kg[Guinea pig].
3. Hazards Identification
Slightly hazardous in case of skin contact (irritant), of eye contact (irritant). Severe over-exposure can result in
death.
Potential Chronic Health Effects:
CARCINOGENIC EFFECTS: Not available.
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male
[POSSIBLE]. Classified Development toxin [NONE].
The substance is toxic to liver, endocrine.
4. First Aid Measures
Eye Contact: NO known EFFECT on eye contact, rinse with water for a few minutes.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated
clothing before reusing.
Serious Skin Contact: Not available.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
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MK 1003 MSDS 1286
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resuscitation. Seek medical attention.
Ingestion:Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is notbreathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Serious Ingestion: Not available.
5. Fire Fighting Measures
Flammability of the Product: May be combustible at high temperature.
Auto-Ignition Temperature: Not available.
Flash Points: Not available.
Flammable Limits: Not available.
Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2.).
Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of open flames and sparks.
Explosion Hazards in Presence of Various Substances:
Risks of explosion of the product in presence of mechanical impact: Not available.
Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media and Instructions:
SMALL FIRE: Use DRY chemical powder.
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
Special Remarks on Fire Hazards: Not available.
Special Remarks on Explosion Hazards: Not available.
6. Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill: Use a shovel to put the material into a convenient waste disposal container.
7. Handling and Storage
Precautions:
Keep locked up Keep away from heat Keep away from sources of ignition. Empty containers pose a fire risk,
evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not
breathe dust Wear suitable protective clothing If ingested, seek medical advice immediately and show the
container or the label.
Storage:
Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly
closed. Keep in a cool, well-ventilated place. Highly toxic or infectious materials should be stored in a separate
locked safety storage cabinet or room.
8. Exposure Controls/Personal Protection
Engineering Controls:
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below
recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to
airborne contaminants below the exposure limit.
Personal Protection: Safety glasses. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Personal Protection in Case of a Large Spill:
Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used
to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist
BEFORE handling this product.
Exposure Limits: Not available.
9. Physical and Chemical Properties
Physical state and appearance: Solid.
Odor: Not available.
Taste: Not available.
Molecular Weight: 531.48 g/mole
Color: White Crystal Powder
pH (1% soln/water): Not available.
Boiling Point: Not available.
Melting Point: Not available.
Critical Temperature: Not available.
Specific Gravity: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Volatility: Not available.
Odor Threshold: Not available.
Water/Oil Dist. Coeff.: Not available.
Ionicity (in Water): Not available.
Dispersion Properties: Not available.
Solubility: Not available.
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MK 1003 MSDS 1286
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10. Stability and Reactivity
Stability: The product is stable.
Instability Temperature: Not available.
Conditions of Instability: Not available.
Incompatibility with various substances: Not available.
Corrosivity: Non-corrosive in presence of glass.
Special Remarks on Reactivity: Not available.
Special Remarks on Corrosivity: Not available.
Polymerization: No.
11. Toxicological Information
Routes of Entry: Absorbed through skin. Eye contact. Ingestion.
Toxicity to Animals: Acute oral toxicity (LD50): 166 mg/kg [Rat].
Chronic Effects on Humans:
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Reproductive system/toxin/male
[POSSIBLE]. Classified Development toxin [NONE].
The substance is toxic to liver, endocrine.
Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant).
Special Remarks on Toxicity to Animals: Not available.
Special Remarks on Chronic Effects on Humans: Not available.
Special Remarks on other Toxic Effects on Humans: Not available.
12. Ecological Information
Ecotoxicity: Not available.
BOD5 and COD: Not available.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.
Special Remarks on the Products of Biodegradation: Not available.
13. Disposal Considerations
Waste Disposal: Disposal must meet local, state and federal guidelines.
14. Transport Information
DOT Classification: Class 6.1: Poisonous material.
Identification: Shipping name: Toxic Solid, Organic, n.o.s. (Ketoconazole) UNNA: UN2811 PG: III
Special Provisions for Transport: Not available.
15. Regulatory Information
Federal and State Regulations: No products were found.
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada): Class D-1B: Material causing immediate and serious toxic effects (TOXIC).
DSCL (EEC):
R25- Toxic if swallowed.
R40- Possible risks of irreversible
effects.
62- Possible risk of impaired fertility.
HMIS (U.S.A.):
Health Hazard: 3
Fire Hazard: 1
Reactivity: 0
Personal Protection: E
National Fire Protection Association (U.S.A.):
Health: 3
Flammability: 1
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Safety glasses.
16. Other Information
References: Not available.
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MK 1003 MSDS 1286
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Other Special Considerations: Not available.
Status:
Reviewed
Reviewed By:
PRP
Review Date:
11/02/2007
********************************************************************************************
DISLAIMER:
National Biochemicals Corp. provides the information contained herein in good faith but makes no representation as to its
comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of
the material by a properly trained person using this product. Individuals receiving the information must exercise their
independent judgment in determining its appropriateness for a particular purpose. NATIONAL BIOCHEMICALS CORP.
MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT
LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH
RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION
REFERS. ACCORDINGLY, NATIONAL BIOCHEMICALS CORP. WILL NOT BE RESPONSIBLE FOR DAMAGES
RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION.
********************************************************************************************

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MK 1003 MSDS 1286
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Source: http://www.nationalbiochem.com/pdf/msds/MK1003%20MSDS.pdf

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